为进一步明晰高速公路路域土壤重金属污染特征和评估其生态风险,以G25长春至双辽段、G12白城至松原段和松原至长春段高速公路为例,分别沿公路走向,按到公路不同距离采集表层土壤样品,利用ICP-OES和ICP-MS测定土壤重金属(As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn)含量,通过应用SPSS对数据统计分析,分别采用内梅罗指数法、地质累积指数法及潜在生态危害指数法进行污染评价。结果表明:9种土壤重金属平均含量均大于其对照样,受公路交通影响比较明显;随着到公路距离的增加,土壤重金属含量基本在30m以内达到峰值,但不同重金属出现峰值的位置不同,总体呈减少的趋势;G12两段高速公路路域土壤出现砷污染,其他土壤重金属尚未达到污染水平;从潜在生态危害指数值来看,3段高速公路重金属污染均属于中等生态危害,说明高速公路运营增加了路域土壤重金属污染生态风险。为此,交通行业应加强高速公路占地界内和占地界外土壤重金属含量对比分析,为科学的污染防控和治理提供依据。
In order to further clarify the heavy metal pollution characteristics of roadside soil along expressway and assess its ecological risk, taking Changchun-Shuangliao section of G25 expressway, Baicheng-Songyuan and Songyuan-Changchun section of G12 Expressway as examples, topsoil samples were collected along the road direction and at different distances from the expressway. Concentrations of soil heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn) were determined by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and Mass Spectrometry (ICP-MS). The data were analyzed by SPSS, and the assessment methods of Nemerow index, Geo-accumulation index and potential ecological risk index were used to evaluate the heavy metal pollution. The results showed that the average concentrations of nine soil heavy metals were higher than those in the control, indicating that heavy metals contents were obviously affected by road traffic. With the increasing of distance from the expressway, the concentrations of soil heavy metals tended to decrease in general. The content of heavy metals in soil basically reached the peak within 30m away from the expressway, but the peak positions of different heavy metals were different. Except that arsenic pollution occurred in the soil along 2 sections of G12 expressway, other soil heavy metals had not reached the pollution level. Based on the results of potential ecological risk index, the roadside soil heavy metal pollutions of the three sections of 2 expressways had reached medium ecological risk level, which indicated that the construction and operation of expressway increased the ecological risk of heavy metal pollution. The transportation industry should strengthen the comparative analysis of soil heavy metal content within and outside the land occupation boundary of expressway, so as to provide basis for scientific pollution prevention and control.
[1] 王新军,高硕晗,姚嘉林,等. 公路路面灰尘及其径流重金属污染研究[J]. 交通运输研究,2018,4(6):62-68.
[2] 陈能场,郑煜基,何晓峰,等. 《全国土壤污染状况调查公报》探析[J]. 农业环境科学学报,2017,36(9):1689-1692.
[3] 郭广慧,陈同斌,宋波,等. 中国公路交通的重金属排放及其对土地污染的初步估算[J]. 地理研究,2007,26(5):922-930.
[4] 新华网. 我国高速通车里程全球第一 路网密度突飞猛进[EB/OL]. (2018-08-17)[2020-10-30].
[5] 国务院. 国务院关于印发土壤污染防治行动计划的通知[EB/OL]. (2016-05-31)[2020-10-30].
[6] LAGERWERFF J V, SPECHT A W. Contamination of roadside soil and vegetation with Cadmium, Nickel, Lead, and Zinc[J]. Environmental Science and Technology, 1970, 4(7): 583-586.
[7] TURER D J, MAYNARD B. Heavy metal contamination in highway soils. Comparison of Corpus Christi, Texas and Cincinnati, Ohio shows organic matter is key to mobility[J]. Clean Technologies and Environmental Policy, 2003, 4(4): 235-245.
[8] FAKAYODE S O, OLU-OWOLABI B I. Heavy metal contamination of roadside topsoil in Osogbo, Nigeria: Its relationship to traffic density and proximity to highways[J]. Environmental Geology, 2003, 44(2): 150-157.
[9] ZEHETNER F, ROSENFELLNER U, GERZABEK M M H. Distribution of road salt residues, heavy metals and polycyclic aromatic hydrocarbons across a highway-forest interface[J]. Water, Air, and Soil Pollution, 2009, 198: 125-132.
[10] GUNEY M, ONAY T T, COPTY N K. Impact of overland traffic on heavy metal levels in highway dust and soils of Istanbul, Turkey[J]. Environmental Monitoring and Assessment, 2010, 164(1-4): 101-110.
[11] KLUGE B, WESSOLEK G. Heavy metal pattern and solute concentration in soils along the oldest highway of the World-the AVUS Autobahn[J]. Environmental Monitoring and Assessment, 2012, 184(11): 6469-6481.
[12] AHMED F, FAKHRUDDIN A N M, Imam M D T, et al. Spatial distribution and source identification of heavy metal pollution in roadside surface soil: A study of Dhaka Aricha Highway, Bangladesh[J]. Ecological Processes, 2016, 5(2): 1-16.
[13] HOSSEINI N S, SOBHANARDAKANI S, CHE-RAGHI M, et al. Heavy metal concentrations in roadside plants (Achillea wilhelmsii and Cardaria draba) and soils along some highways in Hamedan, west of Iran[J]. Environmental Science and Pollution Research, 2020, 27(12): 13301-13314.
[14] LEGRET M, PAGOTTO C. Heavy metal deposition and soil pollution along two major rural highways[J]. Environmental Technology, 2006, 27(3): 247-254.
[15] VIARD B, PIHAN F, PROMEYRAT S, et al. Integrated assessment of heavy metal (Pb, Zn, Cd) highway pollution: Bioaccumulation in soil, graminaceae and land snails[J]. Chemosphere, 2004, 55(10): 1349-1359.
[16] BAI J H, CUI B S, WANG Q G, et al. Assessment of heavy metal contamination of roadside soils in Southwest China[J]. Stochastic Environmental Research and Risk Assessment, 2009, 23(3): 341-347.
[17] 邵莉,肖化云,李南,等. 高速公路沿线路面灰尘及土壤中重金属污染特征研究[J]. 地球与环境,2013,41(6):661-668.
[18] 谷蕾,仝致琦,宋博,等. 基于不同通车时间的路旁土壤重金属健康风险:以连霍高速郑州—商丘段为例[J]. 环境科学,2012,33(10):3577-3584.
[19] 仝致琦,谷蕾,段海静,等. 基于Kriging 插值的路旁土壤重金属含量空间分布――以310 国道郑州-开封段为例[J]. 环境科学学报,2012,32(12):3030-3038.
[20] 季辉,赵健,冯金飞,等. 高速公路沿线农田土壤重金属总量和有效态含量的空间分布特征及其影响因素分析[J]. 土壤通报,2013,44(2):477-483.
[21] 李丰旭. 高速公路沿线农田重金属污染特征及环境风险评价[D]. 长春:东北师范大学,2019.
[22] ZHANG H, WU C Q, GONG J P, et al. Assessment of heavy metal contamination in roadside soils along the Shenyang-Dalian Highway in Liaoning Province, China[J]. Polish Journal of Environmental Studies, 2017, 26(4): 1539-1549.
[23] 刘晓茹. 公路路域农田土壤—农作物重金属污染研究[D]. 西安:长安大学,2012.
[24] WANG H, NIE L, XU Y, et al. The effect of highway on heavy metal accumulation in soil in turfy swamps, Northeastern China[J]. Water Air and Soil Pollution, 2017, 228(8): 292.
[25] 翟云波,戴青云,蒋康,等. 高速公路土壤重金属污染状况及健康风险评价[J]. 湖南大学学报(自然科学版),2016,43(6):149-156.
[26] 周怡,胡文友,黄标,等. 我国高速公路周边土壤重金属污染现状及研究进展[J]. 中国环境监测,2020,36(5):112-120.
[27] JOHANSSON C, NORMAN M G, BURMAN L. Road traffic emission factors for heavy metals[J]. Atmospheric Environment, 2009, 43(31): 4681-4688.
[28] NEMEROW N L. Scientific Stream Pollution Analysis[M]. Washington DC: Scripts Book Company, 1974.
[29] 王玉军,吴同亮,周东美,等. 农田土壤重金属污染评价研究进展[J]. 农业环境科学学报,2017,36(12):2365-2378.
[30] 生态环境部,国家市场监督管理总局. 土壤环境质量 农用地土壤污染风险管控标准(试行):GB 15618—2018 [S]. 北京:中国环境科学出版社,2018.
[31] MULLER G. Index of geoaccumulation in sediment of the Rhine River[J]. Journal of Geology, 1969, 2(3): 108-118.
[32] 柴世伟,温琰茂,张亚雷,等. 地积累指数法在土壤重金属污染评价中的应用[J]. 同济大学学报(自然科学版),2006,34(12):1657-1661.
[33] 王学锋,姚远鹰. 107国道两侧土壤重金属分布及潜在生态危害研究[J]. 土壤通报,2011,42(1):174-178.
[34] 徐争启,倪师军,庹先国,等. 潜在生态危害指数法评价中重金属毒性系数计算[J]. 环境科学与技术,2008,31(2):112-115.
[35] 林丽钦. 应用毒理学安全评价数据推算重金属毒性系数的探讨[C]// 重金属污染监测、风险评价及修复技术高级研讨会. 青岛:中华环保联合会,2009,57-60.
[36] 魏复盛,陈静生,吴燕玉. 中国土壤元素背景值[M]. 北京:中国环境科学出版社,1990.
[37] 赵子良,董桂芳,李振祥,等. 吉林地区自然土壤中九种重金属背景值的研究[J]. 土壤,1987,6(7):315-317.
[38] DE SILVA S, BALL A S, HUYNH T, et al. Metal accumulation in roadside soil in Melbourne, Australia: Effect of road age, traffic density and vehicular speed[J]. Environmental Pollution, 2016, 208(Pt A): 102-109.
[39] 孟宪丽. GIS支持下的吉林省黑土区土壤重金属污染评价研究[D]. 长春:东北师范大学,2008.
[40] 谢忠雷,王筱涵,李娜,等. 吉林省耕地土壤重金属污染研究现状及展望[J]. 吉林农业大学学报,2018,40(4):457-462.
[41] 宋吉明,侯春芳. 汽车尾气中的铅在公路旁水稻叶片中的积累[J]. 环境保护科学,1985,11(1):40-42.
[42] WANG X J, GAO S H, LI H, et al. Investigation of heavy metal contents of road-deposited sediment in expressways[C]// Transportation Research Board 94th Annual Meeting. Washington DC: Transportation Research Board, 2015.