生物油基再生剂的研制及其对再生沥青混合料的性能影响

冯新军; 廖思乐; 段湖杰

doi:10.16503/j.cnki.2095-9931.2025.03.007

PDF(2705 KB)

交通运输研究 ›› 2025, Vol. 11 ›› Issue (3) : 71-83. DOI: 10.16503/j.cnki.2095-9931.2025.03.007

技术前沿

生物油基再生剂的研制及其对再生沥青混合料的性能影响

作者信息 +

Development of Bio-oil-based Regenerant and Its Effect on the Performance of Recycled Asphalt Mixture

Author information +

文章历史 +

摘要

为了研制更加环保且抗老化性能良好的生物油基再生剂，采用椰子油作为生物油基再生剂的基础油分，增塑剂DOP、增黏树脂C9、抗氧化剂PG作为再生剂的原材料。通过正交试验与极差分析，确定生物油基再生剂（SW）中各组分最佳比例。测试SW再生剂的黏度、闪点、薄膜烘箱老化前后质量变化及黏度比，通过针入度法测试SW再生剂的渗透性能，并与某商用再生剂（T）进行比较。通过车辙试验、浸水马歇尔试验、冻融劈裂试验、小梁弯曲试验和劈裂试验，对SW再生沥青混合料的高温稳定性、水稳定性、低温抗裂性、抗老化性能进行评价，并与原样沥青混合料和T再生沥青混合料作对比。结果表明：SW再生剂中各组分最佳比例为椰子油∶增塑剂∶增黏树脂∶抗氧化剂=1.00∶0.20∶0.03∶0.02；SW再生剂的黏度与闪点均满足规范，且抗老化性能与渗透性能优于T再生剂更为优良；SW再生沥青混合料的高温稳定性、水稳定性和低温抗裂性均满足规范要求，高温稳定性与原样沥青混合料相差不大，且低温抗裂性能、抗老化性能以及冻融循环后的水稳定性能均优于原样沥青混合料与T再生沥青混合料。

Abstract

To develop a more environmentally friendly bio-oil-based regenerant with superior anti-aging performance, coconut oil was selected as the base oil, and Plasticizer DOP, tackifying resin C9, and antioxidant PG were incorporated as raw materials for the regenerant. Through orthogonal test and range analysis, the optimal proportion of each component in bio-oil based regenerant (SW) was determined. The viscosity, flash point, mass change before and after aging in the film oven and viscosity ratio of SW regenerant were tested. The penetration performance of SW regenerant was tested by the needle penetration method, and compared with a commercial regenerant (T). Through rut test, immersion Marshall test, freeze-thaw split test, trabecular bending test and split test, the high temperature stability, water stability, low temperature crack resistance and aging resistance of SW recycled asphalt mixture were evaluated, and compared with the original asphalt mixture and T recycled asphalt mixture. The results show that the optimal proportion of each component in SW regenerant is coconut oil: plasticizer: tackifying resin: antioxidant=1.00∶0.20∶0.03∶0.02. The viscosity and flash point of SW regenerant meet the specifications, and the aging resistance and penetration performance are better than those of T regenerant. The high temperature stability, water stability and low temperature cracking resistance of SW recycled asphalt mixture all meet the requirements of the specification. The high temperature stability is not much different from that of the original asphalt mixture. The low temperature cracking resistance, aging resistance and water stability after freeze-thaw cycle are better than those of the original asphalt mixture and T recycled asphalt mixture.

导出引用

冯新军, 廖思乐, 段湖杰. 生物油基再生剂的研制及其对再生沥青混合料的性能影响[J]. 交通运输研究. 2025, 11(3): 71-83 https://doi.org/10.16503/j.cnki.2095-9931.2025.03.007

FENG Xinjun, LIAO Sile, DUAN Hujie. Development of Bio-oil-based Regenerant and Its Effect on the Performance of Recycled Asphalt Mixture[J]. Transport Research. 2025, 11(3): 71-83 https://doi.org/10.16503/j.cnki.2095-9931.2025.03.007

中图分类号： U414

参考文献

列表( 原文顺序 | 文献年度倒序 | 文中引用次数倒序 ) 可视化分析

[1]	郭鹏, 谢凤章, 孟建玮, 等. 沥青再生过程中新-旧沥青界面混溶行为综述[J]. 材料导报, 2020, 34(13):13100-13108.

[2]	王杰, 秦永春, 曾蔚, 等. 多次再生沥青混合料沥青组分迁移及其性能[J]. 建筑材料学报, 2020, 23(1):77-84.

[3]	闫正和, 张启志. 生物油再生剂热再生老化SBS改性沥青及混合料性能研究[J]. 新型建筑材料2020, 47(3):83-87.

[4]	侯芸, 董元帅, 李志豪, 等. 植物油再生SBS改性沥青混合料路用性能研究[J]. 重庆交通大学学报(自然科学版), 2021, 40(8):120-125.

[5]	任文芳. 生物再生剂再生沥青流变性能研究[J]. 公路交通科技(应用技术版), 2020, 16(3):70-75.

[6]	唐伯明, 曹芯芯, 朱洪洲, 等. 生物油再生沥青胶结料路用性能分析[J]. 中国公路学报, 2019, 32(4):207-214.

[7]	DEVULAPALLI L, KOTHANDARAMAN S, SA-RANG G. Evaluation of rejuvenator′s effectiveness on the recycled asphalt pavement incorporated stone matrix asphalt mixtures[J]. Construction and Building Materials, 2019, 224: 909-919.

[8]	PODOLSKY J, CHEN C, HERNÁNDEZ N, et al. Low temperature performance of HMA using vacuum tower distillation bottoms modified with bio-derived rejuvenators according to the SCB test[J]. International Journal of Pavement Engineering, 2020, 23(2): 231-239.

[9]	TABATABAEE H, KURTH T. Analytical investigation of the impact of a novel bio-based recycling agent on the colloidal stability of aged bitumen[J]. Road Materials & Pavement Design, 2017, 18(2): 1-10.

[10]	PERALTA J, WILLIAMS R, ROVER M. Development of a rubber-modified fractionated bio-oil for use as noncrude petroleum binder in flexible pavements[J]. Transportation Research Circular E-165, 2012, 165: 23-36.

[11]	MOHAMED E, WILLIAMS R, ERIC W, et al. Thermal and cold flow properties of bio-derived rejuvenators and their impact on the properties of rejuvenated asphalt binders[J]. Thermochimica Acta, 2018, 671: 48-53.

[12]	GAO J, WANG H, YOU Z, et al. Research on properties of bio-asphalt binders based on time and frequency sweep test[J]. Construction and Building Materials, 2018, 160: 786-793.

[13]	CAO Z, CHEN M, LIU Z, et al. Effect of different rejuvenators on the rheological properties of aged SBS modified bitumen in long term aging[J]. Construction and Building Materials, 2019, 215: 709-717.

[14]	欧阳自强, 朱建勇, 袁泉, 等. 沥青再生剂性能研究与评价[J]. 中外公路, 2016(5):294-299.

[15]	LIN P, YAN C, HUANG W, et al. Rheological, chemical and aging characteristics of high content polymer modified asphalt[J]. Construction and Building Materials, 2019, 207: 616-629.

[16]	梁庆, 郑云, 张关发, 等. 废机油再生SBS改性沥青性能及再生机理[J]. 科学技术与工程, 2023, 23(2):777-784.

[17]	SU N, XIAO F, WANG J, et al. Productions and applications of bio-asphalts-A review[J]. Construction and Building Materials, 2018, 183: 578-591.

[18]	LI X, ZHANG R, ZHAO X, et al. Sensitivity analysis of flexible pavement parameters by mechanistic-empirical design guide[J]. Applied Mechanics and Materials, 2014, 590: 539-545.

[19]	刘崇麟, 蒋康, 吴超凡, 等. 木焦油基再生沥青低温性能评价及其作用机理分析[J]. 建筑材料学报, 2021, 24(6):1255-1264.

[20]	斯李. 糠醛抽出油对不同老化程度沥青的再生效果研究[D]. 广州: 华南理工大学, 2021.

[21]	丁婕. 道路沥青五次老化再生微观分析[D]. 湘潭: 湖南科技大学, 2015.

[22]	AYAKC G, TEKIN K, AKALIN M, et al. Production of crude bio-oil and biochar from hydrothermal conversion of jujube stones with metal carbonates[J]. Biofuels, 2018, 9(5): 613-623.